Sunday, January 23, 2011

Group 3 elements

The Group 3 elements are chemical elements comprising the third vertical column of the periodic table.
IUPAC has not recommended a specific format for the periodic table, so different conventions are permitted and are often used for group 3. The following d-block transition metals are always considered members of group 3:
•    scandium (Sc)
•    yttrium (Y)

Scandium (Sc)

Yttrium (Y)

When defining the remainder of group 3, four different conventions may be encountered:

  • Some tables  include lanthanum (La) and actinium (Ac), (the beginnings of the lanthanide and actinide series of elements, respectively) as the remaining members of group 3. In their most commonly encountered tripositive ion forms, these elements do not possess any partially filled f orbitals, thus resulting in more d-block-like behavior.
  • Some tables include lutetium (Lu) and lawrencium (Lr) as the remaining members of group 3. These elements terminate the lanthanide and actinide series, respectively. Since the f-shell is nominally full in the ground state electron configuration for both of these metals, they behave most like d-block metals out of all the lanthanides and actinides, and thus exhibit the most similarities in properties with Sc and Y. For Lr, this behavior is expected, but it has not been observed because sufficient quantities are not available. (See also Periodic table (wide) and Periodic table (extended).)
Some tables  refer to all lanthanides and actinides by a marker in group 3. A third and fourth alternative are suggested by this arrangement:
  • The third alternative is to regard all 30 lanthanide and actinide elements as included in group 3. Lanthanides, as electropositive trivalent metals, all have a closely related chemistry, and all show many similarities to Sc and Y.
  • The fourth alternative is to include none of the lanthanides and actinides in group 3. The lanthanides possess additional properties characteristic of their partially-filled f orbitals which are not common to Sc and Y. Furthermore, the actinides show a much wider variety of chemistry (for instance, in range of oxidation states) within their series than the lanthanides, and comparisons to Sc and Y are even less useful.
The term rare earth elements is often used for group 3 elements including the lanthanides but excluding the actinides.

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